Studies on preparation of metalloporphyrin‐functionalized PVI and PVI/SiO2 via axial coordination reaction

Cobalt tetraphenylporphyrin (CoTPP) was bond on the side chains of poly(N‐vinylimidazole) (PVI) and immobilized on PVI/SiO₂ via axial coordination reactions, respectively, leading to the soluble metalloporphyrin‐functionalized PVI (denoted as CoTPP–PVI) and the particles CoTPP–PVI/SiO₂. The above two target products were characterized using spectroscopy methods such as infrared spectrum, electronic absorption spectrum, and fluorescence emission spectrum. And the effects of various factors on the bonding reaction and immobilization reaction of CoTPP were studied in detail. The experimental results show that CoTPP–PVI and CoTPP–PVI/SiO₂ can be prepared favorably through axial coordination reaction of CoTPP with the side imidazole groups of PVI and PVI/SiO₂. In addition, the soluble CoTPP–PVI has all the spectral characteristics of CoTPP. As compared to CoTPP, the adsorption spectra of CoTPP–PVI exhibit red shift obviously. In the immobilization process of CoTPP on PVI/SiO₂, the higher the concentrations of CoTPP and the reaction temperature, the greater the immobilization amount of CoTPP is. Copyright © 2009 John Wiley & Sons, Ltd.     

The F band of mixed ionic crystals as a function of temperature

Abstract

Experimental and theoretical study of the F absorption band were carried out in mixed ionic crystals as a function of temperature and molar composition. Both the point-ion and pseudopotential methods of Gourary–Adrian and Bartram–Stoneham–Gash, respectively, have been used to obtain the F band shift effect in KCl_1?x Br _x mixed crystals with molar fraction x and the temperature T of the crystal. The theoretical values were compared with the experimental ones, and a good agreement between experimental and theoretical calculations has been found.     

Influence of SiO_3~（2-）Impurity on the Optical Properties of KDP Crystal

In this paper,potassium dihydrogen phosphate(KDP) crystals were grown in the presence of a series of silicate(SiO32-) impurity concentrations via conventional temperature cooling and rapid growth methods,respectively.It revealed that the SiO32-impurity could lead to the decrease of transmittance at the region of ultraviolet band for pyramidal sectors and slightly increased the transmittance for prismatic sectors.SiO32-could enter into the crystal lattice and create lattice defects,which consequently increased the density of light scatter.The decrease of laser damage threshold was attributed to the lattice defects and the redundant electrons brought by the replacement of SiO32-at the PO43-position.     

Protonation‐Assisted Conjugate Addition of Axially Chiral Enolates: Asymmetric Synthesis of Multisubstituted β‐Lactams from α‐Amino Acids

β‐Lactams with contiguous tetra‐ and trisubstituted carbon centers were prepared in a highly enantioselective manner through 4‐exo‐trig cyclization of axially chiral enolates generated from readily available α‐amino acids. Use of a weak base (metal carbonate) in a protic solvent (EtOH) is the key to the smooth production of β‐lactams. Use of the weak base is expected to generate the axially chiral enolates in a very low concentration, which undergo intramolecular conjugate addition without suffering intermolecular side reactions. Highly strained β‐lactam enolates thus formed through reversible intramolecular conjugate addition (4‐exo‐trig cyclization) of axially chiral enolates undergo prompt protonation by EtOH in the reaction media (not during the work‐up procedure) to give β‐lactams in up to 97 % ee.     

Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination

Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the formation of type?I quintuple-bonded complexes.     

Preparation of NaCl color center laser crystals and perturbation effect of ions

NaCl:(F₂⁺)_AH-type color center laser crystals were prepared by the crystal growth, additional coloration, annealing, and by light aggregation at 290 and 77 K. The formation process of color center in NaCl crystals were investigated, the influence of doped cation and anion ions on the stability and optical properties of color centers is discussed in this paper.     

基于喷管节流的轴流转子非轴对称间隙布局研究

实际工作中的压气机转子叶尖间隙往往存在着非轴对称性,对压气机性能及稳定性产生影响.本文以上海交通大学LSRC压气机实验台的第一级转子为研究对象,开展了转子非轴对称间隙布局的数值模拟研究.在数值模拟中,通过在转子出口设置喷管的方式模拟节流过程,分析了喷管结构对压气机性能的影响,并对该方法与常规背压节流方法进行了对比验证....     

Extended defects in bulk GaN and III-nitrides grown on this substrate

A short review of the structural perfection of high-pressure grown bulk crystals is given. As-grown undoped and Mg-doped crystals are described. The dependence of defect arrangement and quality of the surface on growth polarity is described. A high perfection of homoepitaxial layers grown on these substrates is shown. However, growth of thick layers by HVPE may lead to the formation of differently arranged dislocations and the formation of low angle grain boundaries associated with cracks. It is shown that the introduction of dopant or growth of mismatched layers on undoped high-pressure substrates may lead to the formation of additional defects.     

低速轴流压气机中工况变化对动叶顶部泄漏流波动频率的影响

本文利用数值方法研究了某两级低速轴流压气机第二级动叶在存在前后静叶扰动时,工况变化对其顶部非定常泄漏流波动频率的影响。结果显示其波动主要集中在泄漏涡轨迹附近,并且随着流量减小而增强。在大流量工况,其波动频率为转子通道频率。在中等流量工况,其波动频率为0.59倍通道频率。在小流量工况,其波动频率为0.51倍通道频率。并且其波动频率与前后静叶扰动强度无关。